1,4-Dihydro-1,4-methanonaphthalene

CAS No. 4453-90-1
Cat. No. CS-B0002
Purity≥98%
MDL No.MFCD00213597

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FedEx Limited Quantities Ground	$0.00
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1,4-Dihydro-1,4-methanonaphthalene|CS-B0002

Structure of 4453-90-1

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Description

1,4-Dihydro-1,4-methanonaphthalene features a rigid, fused bicyclic structure with localized diene character, enabling participation in Diels-Alder cycloadditions. This bench-stable, moisture-tolerant intermediate integrates readily into synthetic sequences requiring controlled reactivity and defined stereochemistry.

Application

1,4-Dihydro-1,4-methanonaphthalene serves as a versatile bicyclic building block in synthetic organic chemistry, offering enhanced rigidity and defined stereochemistry. Its stable dihydroaromatic core facilitates functionalization at the olefinic positions and enables selective transformations under standard catalytic conditions. The molecule functions effectively in transition-metal-catalyzed couplings and serves as a scaffold for heterocyclic systems and complex molecular architectures relevant to medicinal chemistry and materials science.

General Information

CAS No. 4453-90-1
Cat. No. CS-B0002
Purity ≥98%
MDL No. MFCD00213597
Storage 4°C
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₁₁H₁₀
Molecular Weight 142.20
Synonym(s) Tricyclo[6.2.1.02,7]undeca-2,4,6,9-tetraene
SMILES C12C3=CC=CC=C3C(C=C2)C1

Computational Chemistry Data

TPSA 0
LogP 2.8273
H_Acceptors 0
H_Donors 0
Rotatable_Bonds 0

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P280-P330

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Other Classifications

Building Blocks Skeleton Bridge Rings compounds Other bridge ring compounds

Material Science Polymer Materials Macromolecular Monomer

Material Science Polymer/Macromolecule Reagents Monomers Cyclic Olefin Monomers

Key Words

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1,4-Dihydro-1,4-methanonaphthalene

CAS No. 4453-90-1

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