2-Amino-6-fluorobenzamide

Name: 2-Amino-6-fluorobenzamide
Brand: ChemScene
Availability: InStock
Rating: 5 (1 reviews)

CAS No. 115643-59-9
Cat. No. CS-0186546
Purity≥98%
MDL No.None

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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Structure of 115643-59-9

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General Information

CAS No. 115643-59-9
Cat. No. CS-0186546
Purity ≥98%
MDL No. None
Storage RT, protect from light
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₇H₇FN₂O
Molecular Weight 154.14
Synonym(s) None
SMILES NC1=CC=CC(F)=C1C(N)=O

Description

2-Amino-6-fluorobenzamide features a fluorine atom at the para position relative to the amide group, enhancing electronic effects and metabolic stability. The amino group enables direct coupling in peptide synthesis and conjugation workflows. This bench-stable derivative integrates readily into bioactive scaffolds for medicinal chemistry campaigns.

Application

2-Amino-6-fluorobenzamide serves as a versatile building block in medicinal chemistry, enabling the construction of bioactive heterocycles and peptide-like scaffolds. Its ortho-amino and fluoro substituents provide complementary reactivity for palladium-catalyzed couplings, electrophilic substitutions, and cyclization reactions. The compound exhibits excellent bench stability and facilitates straightforward purification, making it well-suited for scalable synthesis and API development workflows.

Synthesis

Route1
- In-stock
  
  77326-36-4
- ~10%
- In-stock
  
  115643-59-9
References
- Tu, Tao; Wang, Zhixun; Liu, Zelong; Feng, Xike; Wang, Qingyi Green Chemistry, 2012 , vol. 14, # 4 p. 921 - 924
Route2
- In-stock
  
  79544-29-9
- ~%
- In-stock
  
  115643-59-9
References
- Journal of Chemical Sciences, , vol. 125, # 1 p. 71 - 83

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302
Precautionary Statements : P264-P270-P501

Quality Control

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Computational Chemistry Data

TPSA 69.11
LogP 0.5068
H_Acceptors 2
H_Donors 2
Rotatable_Bonds 1

Other Classifications

Building Blocks Functional Group Fluoride

Building Blocks Functional Group Amide

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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2-Amino-6-fluorobenzamide

CAS No. 115643-59-9

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