{N-[3-(η6-phenyl)propyl]-[(1R-2R)-1,2-diphenyl-1-4-methylbenzenesulfonylamidato(kN')-ethyl-2-amino-(kN)]}ruthenium(II)

Name: {N-[3-(η6-phenyl)propyl]-[(1R-2R)-1,2-diphenyl-1-4-methylbenzenesulfonylamidato(kN')-ethyl-2-amino-(kN)]}ruthenium(II)
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CAS No. 1192620-83-9
Cat. No. CS-M3303
Molecule weight620.17
Purity≥98%
MDL No.MFCD16294993

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{N-[3-(η6-phenyl)propyl]-[(1R-2R)-1,2-diphenyl-1-4-methylbenzenesulfonylamidato(kN')-ethyl-2-amino-(kN)]}ruthenium(II)|CS-M3303

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General Information

CAS No. 1192620-83-9
Cat. No. CS-M3303
Purity ≥98%
MDL No. MFCD16294993
Storage 4°C, protect from light, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₃₀H₃₁ClN₂O₂RuS
Molecular Weight 620.17
Synonym(s) Chloro[N-[(1R,2R)-1,2-diphenyl-2-[[3-(eta6-phenyl)propyl]amino]ethyl]-4-methylbenzenesulfonamidato]ruthenium
SMILES Cl[Ru]([N@@]1([H])CCCC2=CC=CC=C2)N([C@H](C3=CC=CC=C3)[C@H]1C4=CC=CC=C4)S(C5=CC=C(C)C=C5)(=O)=O

Description

This ruthenium(II) complex features a chiral diphenylmethylsulfonylamido ligand coordinated through nitrogen, paired with an η⁶-phenylpropyl group. The structure integrates a sterically encumbered aromatic scaffold and a pendant amine, enabling selective coordination in catalytic transformations. Bench-stable under inert conditions, it serves as a robust platform for asymmetric synthesis.

Application

This ruthenium(II) complex serves as a robust catalyst for selective C–H functionalization and cross-coupling reactions, leveraging the chelating diphenylsulfonylamido ligand framework to enhance stability and turnover. Its η⁶-phenyl coordination and tailored steric environment facilitate efficient arene activation under mild conditions, enabling reliable construction of biaryl and heteroaromatic scaffolds in medicinal chemistry workflows.

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H315-H319-H335
Precautionary Statements : P261-P280-P304+P340-P405-P501

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Computational Chemistry Data

TPSA 40.62
LogP 7.01872
H_Acceptors 3
H_Donors 0
Rotatable_Bonds 8

Key Words

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{N-[3-(η6-phenyl)propyl]-[(1R-2R)-1,2-diphenyl-1-4-methylbenzenesulfonylamidato(kN')-ethyl-2-amino-(kN)]}ruthenium(II)

CAS No. 1192620-83-9

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