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CS-W001157 4
Total: USD 88.00

RuCl[(R,R)-TsDPEN](mesitylene)

  • CAS No. 174813-82-2

  • Cat. No. CS-0082021
  • Molecule weight622.18
  • Purity≥98%
  • MDL No.MFCD03791031

*For research and further manufacturing use only, not for direct human use.

RuCl[(R,R)-TsDPEN](mesitylene)|CS-0082021

Structure of 174813-82-2

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General Information

  • CAS No. 174813-82-2
  • Cat. No. CS-0082021
  • Purity ≥98%
  • MDL No. MFCD03791031
  • Storage 4°C, protect from light, stored under nitrogen
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₃₀H₃₃ClN₂O₂RuS
  • Molecular Weight 622.18
  • Synonym(s) Chloro(mesitylene)[(R,R)-N-(p-toluenesulfonyl)-1,2-diphenylethylenediamine]ruthenium(II)
  • SMILES Cc1cc(C)cc(C)c1.Cl[Ru]([NH2]2)N([C@H](C3=CC=CC=C3)[C@H]2C4=CC=CC=C4)S(C5=CC=C(C)C=C5)(=O)=O

Application

RuCl[(R,R)-TsDPEN](mesitylene) serves as a highly effective chiral catalyst for asymmetric hydrogenation reactions, enabling enantioselective reduction of prochiral substrates such as enamines and dehydroamino acids. The robust (R,R)-TsDPEN ligand imparts high enantioselectivity, while the mesitylene co-ligand enhances solubility and catalyst stability. This complex facilitates scalable, operationally simple transformations in the synthesis of chiral building blocks relevant to pharmaceutical intermediates.

Safety Information

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GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Computational Chemistry Data

  • TPSA   49.41
  • LogP   7.28538
  • H_Acceptors   3
  • H_Donors   1
  • Rotatable_Bonds   4

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