Methyl 6-amino-4-chloronicotinate

Name: Methyl 6-amino-4-chloronicotinate
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CAS No. 1260666-60-1
Cat. No. CS-0160845
Purity≥98%
MDL No.MFCD18250740

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Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
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Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
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Methyl 6-amino-4-chloronicotinate|CS-0160845

Structure of 1260666-60-1

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General Information

CAS No. 1260666-60-1
Cat. No. CS-0160845
Purity ≥98%
MDL No. MFCD18250740
Storage 4°C, protect from light
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₇H₇ClN₂O₂
Molecular Weight 186.60
Synonym(s) 3-Pyridinecarboxylic acid, 6-amino-4-chloro-, methyl ester
SMILES O=C(OC)C1=CN=C(N)C=C1Cl

Description

Methyl 6-amino-4-chloronicotinate features a strategically positioned amino group flanking a chlorinated pyridine core, enabling direct incorporation into heterocyclic scaffolds. This bench-stable derivative supports efficient derivatization in synthetic routes targeting bioactive compounds and functional materials.

Application

Methyl 6-amino-4-chloronicotinate serves as a versatile building block in medicinal chemistry, enabling direct functionalization at the amino and ester positions. Its electron-deficient pyridine core facilitates palladium-catalyzed cross-coupling reactions, while the amino group offers straightforward derivatization via acylation, alkylation, or diazotization. The compound exhibits excellent bench stability and is readily purified by crystallization or flash chromatography, making it well-suited for scalable synthesis of heterocyclic scaffolds and API intermediates.

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Computational Chemistry Data

TPSA 65.21
LogP 1.1038
H_Acceptors 4
H_Donors 1
Rotatable_Bonds 1

Other Classifications

Building Blocks Functional Group Chloride

Building Blocks Functional Group Ester

Building Blocks Skeleton Aromatic heterocycle compounds Pyridine compounds

Key Words

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Methyl 6-amino-4-chloronicotinate

CAS No. 1260666-60-1

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