Tetrakis(triphenylphosphine)palladium

Name: Tetrakis(triphenylphosphine)palladium
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CAS No. 14221-01-3
Cat. No. CS-W019593
Purity≥98%
MDL No.MFCD00010012

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Tetrakis(triphenylphosphine)palladium|CS-W019593

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Description

Palladium-tetrakis(triphenylphosphine) (Pd(PPh3)4) iscoordination complex of palladium and is widely used palladium cross-coupling catalyst. These applications include Negishi coupling, Suzuki coupling, Stille coupling, Sonogashira coupling, and Buchwald-Hartwig amination reactions. Tetrakis(triphenylphosphine)palladium(0) (Pd(PPh3)4) is a commonly used palladium(0) complex in chemical synthesis. It plays a vital role as a catalyst in various organic reactions, especially C-C, C-N, C-O, and C-heteroatom cross-coupling reactions. Pd(PPh3)4 finds extensive application in carbon-carbon bond-forming reactions such as the famous Heck, Suzuki-Miyaura, and Stille reactions. These reactions involve the coupling of aryl, alkyl, or vinyl halides with other organic compounds to yield valuable products. The catalytic cycle involves the oxidative addition of the organic halide to palladium(0), transmetalation with a suitable organometallic reagent or boronic acid, and reductive elimination to form the desired product. Pd(PPh3)4 has also been utilized in various other transformations including allylic substitutions, nucleophilic additions to alkenes and alkynes, and cycloadditions.Application Guide for Palladium Catalyzed Cross-Coupling Reactions

General Information

CAS No. 14221-01-3
Cat. No. CS-W019593
Purity ≥98%
MDL No. MFCD00010012
Storage -20°C, protect from light, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₇₂H₆₀P₄Pd
Molecular Weight 1155.56
Synonym(s) Tetrakis(triphenylphosphine)palladium(0)
SMILES [Pd][P](C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3.[4]

Computational Chemistry Data

TPSA 0
LogP 13.7767
H_Acceptors 0
H_Donors 0
Rotatable_Bonds 16

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302
Precautionary Statements : P264-P270-P330-P501

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Other Classifications

Bioactive Molecules Dye and Bio-assay Reagents

Catalysts and Ligands Catalysts Transition Metal Catalysts Pd Catalysts

Chemical Biology Glycoscience Reagents for Oligosaccharide Synthesis

Material Science Polymer/Macromolecule Reagents Polymerization Reagents Polymerization Catalysts

Chemical Synthesis Synthetic Reagents C-C Bond Formation Cross-coupling Reaction using Transition Metal Catalysts

Catalysis Asymmetric Synthesis Chiral Catalysts, Chiral Ligands, Chiral Reagents Chiral Catalysts (Other)

Catalysis C-H Activation Palladium Compounds

Catalysis Compounds by Element Classes Metal Compounds Transition Metal Compounds

Catalysis Cross-coupling Reaction using Transition Metal Catalysts Palladium Catalysts

Catalysis Transition Elements Palladium

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Tetrakis(triphenylphosphine)palladium

CAS No. 14221-01-3

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