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CS-W001157 4
Total: USD 88.00

Tris(triphenylphosphine)chlororhodium(I)

  • CAS No. 14694-95-2

  • Cat. No. CS-0035226
  • Molecule weight925.22
  • Purity≥98%
  • MDL No.MFCD00010016

*For research and further manufacturing use only, not for direct human use.

Tris(triphenylphosphine)chlororhodium(I)|CS-0035226

Structure of 14694-95-2

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General Information

  • CAS No. 14694-95-2
  • Cat. No. CS-0035226
  • Purity ≥98%
  • MDL No. MFCD00010016
  • Storage 4°C, protect from light, stored under nitrogen
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₅₄H₄₅ClP₃Rh
  • Molecular Weight 925.22
  • Synonym(s) Wilkinson Catalyst
  • SMILES Cl[Rh][P](C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3

Description

Tris(triphenylphosphine)rhodium(I) chloride is used as a decarbonylation reagent and as a cocatalyst in Heck reaction.Hydrosilylation CatalystsCatalyst used for many organic reactions including:Chemoselective allylic alkylationsStoichiometric activation of Si-H bonds and hydrosilylationsInter- and intramolecular hydroacylation of alkenes along with a cocatalystPolymerization of diorganostannanes

Synthesis

  • Route1
    • (SP-4-3)-Carbonylchlorobis(triphenylphosphine)rhodium|CS-0784514
      15318-33-9
    • ~96%
    • In-stock
      Tris(triphenylphosphine)chlororhodium(I)|CS-0035226
      14694-95-2
    • null|null
      14653-50-0

    References

    • Inorganic Chemistry, , vol. 32, p. 1866 - 1867
  • Route2
    • [Rh(cod)Cl]2, High quality|CS-1383718
      12092-47-6
    • ~%
    • In-stock
      Tris(triphenylphosphine)chlororhodium(I)|CS-0035226
      14694-95-2

    References

    • Journal of Organometallic Chemistry, , vol. 359, p. C22 - C26
  • Route3
    • null|null
      89178-76-7
    • ~55%
    • In-stock
      Tris(triphenylphosphine)chlororhodium(I)|CS-0035226
      14694-95-2

    References

    • Murray, Brendan D.; Hope, Hakon; Hvoslef, Jan; Power, Philip P. Organometallics, 1984 , vol. 3, p. 657 - 663

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H317-H413
Precautionary Statements : P261-P272-P273-P280-P302+P352-P363-P501

Quality Control

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Computational Chemistry Data

  • TPSA   0
  • LogP   3.8641
  • H_Acceptors   0
  • H_Donors   0
  • Rotatable_Bonds   4

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