(2,2'-Bipyridine)dichloropalladium(II)

Name: (2,2'-Bipyridine)dichloropalladium(II)
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CAS No. 14871-92-2
Cat. No. CS-0035156
Purity≥98%
MDL No.MFCD00134305

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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(2,2'-Bipyridine)dichloropalladium(II)|CS-0035156

Structure of 14871-92-2

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Description

This palladium(II) complex features a bipyridine ligand that enhances stability and facilitates oxidative addition in cross-coupling reactions. The dichloro coordination provides controlled reactivity, enabling efficient catalytic cycles under standard conditions.

Application

(2,2'-Bipyridine)dichloropalladium(II) serves as a robust, bench-stable precatalyst for cross-coupling reactions, enabling efficient C–C and C–heteroatom bond formation under mild conditions. Its well-defined coordination sphere enhances reactivity in Suzuki-Miyaura, Negishi, and Stille couplings, while tolerating diverse functional groups. The bipyridine ligand stabilizes the Pd(II) center, facilitating smooth reduction to active Pd(0) species during catalytic cycles.

General Information

CAS No. 14871-92-2
Cat. No. CS-0035156
Purity ≥98%
MDL No. MFCD00134305
Storage 4°C, protect from light, stored under nitrogen
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₁₀H₈Cl₂N₂Pd
Molecular Weight 333.51
Synonym(s) Dichloro(2,2'-bipyridine)palladium
SMILES Cl[Pd]1(Cl)[N]2=C(C3=CC=CC=[N]31)C=CC=C2

Computational Chemistry Data

TPSA N/A
LogP N/A
H_Acceptors N/A
H_Donors N/A
Rotatable_Bonds N/A

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H315-H319-H335
Precautionary Statements : P261-P264-P271-P280-P302+P352-P304+P340-P362-P405-P501

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(2,2'-Bipyridine)dichloropalladium(II)

CAS No. 14871-92-2

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