2-Bromo-4-iodo-1-methoxybenzene

Name: 2-Bromo-4-iodo-1-methoxybenzene
Brand: ChemScene
Availability: InStock
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CAS No. 182056-39-9
Cat. No. CS-0097745
Purity≥97%
MDL No.MFCD03425935

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
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Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
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2-Bromo-4-iodo-1-methoxybenzene|CS-0097745

Structure of 182056-39-9

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Description

2-Bromo-4-iodo-1-methoxybenzene features a strategically positioned methoxy group that enhances solubility and directs electrophilic substitution, while the bromo and iodo substituents enable sequential cross-coupling reactions. This ortho-disubstituted aromatic scaffold serves as a high-precision intermediate for constructing complex biaryl architectures in medicinal chemistry and materials science.

Application

2-Bromo-4-iodo-1-methoxybenzene serves as a versatile dihalogenated aromatic building block for palladium-catalyzed cross-coupling reactions. The bromo and iodo substituents enable sequential functionalization via Suzuki, Stille, or Negishi couplings, while the methoxy group provides electronic modulation and orthogonal reactivity. Its bench-stable crystalline form facilitates handling and purification, making it ideal for constructing complex scaffolds in medicinal chemistry and materials science.

General Information

CAS No. 182056-39-9
Cat. No. CS-0097745
Purity ≥97%
MDL No. MFCD03425935
Storage 4°C, protect from light
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₇H₆BrIO
Molecular Weight 312.93
Synonym(s) 2-Bromo-4-iodophenyl methyl ether
SMILES COC1=CC=C(I)C=C1Br

Computational Chemistry Data

TPSA 9.23
LogP 3.0623
H_Acceptors 1
H_Donors 0
Rotatable_Bonds 1

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Other Classifications

Building Blocks Functional Group Bromide

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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2-Bromo-4-iodo-1-methoxybenzene

CAS No. 182056-39-9

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