Methyl 5-bromo-3-methylpyridine-2-carboxylate

Name: Methyl 5-bromo-3-methylpyridine-2-carboxylate
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CAS No. 213771-32-5
Cat. No. CS-W004188
Purity≥98%
MDL No.MFCD07375126

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Methyl 5-bromo-3-methylpyridine-2-carboxylate|CS-W004188

Structure of 213771-32-5

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Description

Methyl 5-bromo-3-methylpyridine-2-carboxylate features a pyridine core functionalized with bromo, methyl, and ester groups at strategic positions. This trifunctional scaffold enables direct coupling in cross-coupling reactions and serves as a key intermediate in the synthesis of bioactive heterocycles and pharmaceutical candidates. The molecule exhibits enhanced stability under standard bench conditions and compatibility with transition metal catalysis.

Application

Methyl 5-bromo-3-methylpyridine-2-carboxylate serves as a versatile building block in heterocyclic synthesis, enabling palladium-catalyzed cross-coupling reactions at the bromo position. The methyl and ester groups provide orthogonal functionality for further derivatization, while the pyridine core offers favorable electronic properties for medicinal chemistry applications. Bench-stable and readily purified by column chromatography, it facilitates efficient access to substituted pyridine scaffolds relevant to agrochemical and pharmaceutical development.

General Information

CAS No. 213771-32-5
Cat. No. CS-W004188
Purity ≥98%
MDL No. MFCD07375126
Storage Store at room temperature
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₈H₈BrNO₂
Molecular Weight 230.06
Synonym(s) Methyl 5-bromo-3-methylpicolinate
SMILES COC(=O)c1ncc(cc1C)Br

Computational Chemistry Data

TPSA 39.19
LogP 1.93912
H_Acceptors 3
H_Donors 0
Rotatable_Bonds 1

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Other Classifications

Building Blocks Functional Group Ester

Building Blocks Skeleton Aromatic heterocycle compounds Pyridine compounds

Key Words

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Methyl 5-bromo-3-methylpyridine-2-carboxylate

CAS No. 213771-32-5

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