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CS-W001157 4
Total: USD 88.00

1-Bromo-4-(phenylsulfonyl)benzene

  • CAS No. 23038-36-0

  • Cat. No. CS-W006340
  • Purity≥97%
  • MDL No.MFCD00034047

*For research and further manufacturing use only, not for direct human use.

1-Bromo-4-(phenylsulfonyl)benzene|CS-W006340

Structure of 23038-36-0

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General Information

  • CAS No. 23038-36-0
  • Cat. No. CS-W006340
  • Purity ≥97%
  • MDL No. MFCD00034047
  • Storage Store at room temperature
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₁₂H₉BrO₂S
  • Molecular Weight 297.17
  • Synonym(s) Phenyl(4-bromophenyl) sulfone
  • SMILES BrC1=CC=C(C=C1)S(=O)(=O)C1=CC=CC=C1

Description

Metanil Yellow is used as indicator. Metanil yellow is useful in spectrophotometric methods to determine the presence of trace amounts of nitrates and nitrites in solution. The method utilizes the fact that potassium bromate can catalyze the discoloring of Metanil yellow which can then be analyzed by spectrophotometry.

Application

1-Bromo-4-(phenylsulfonyl)benzene serves as a versatile aryl halide building block for palladium-catalyzed cross-coupling reactions, including Suzuki, Stille, and Negishi couplings. The phenylsulfonyl group provides strong electron-withdrawal, enhancing reactivity in nucleophilic substitution processes while maintaining bench stability. Its orthogonal functionalization profile enables efficient construction of biaryl scaffolds and complex heterocyclic systems relevant to medicinal chemistry and materials science applications.

Synthesis

  • Route1
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      7446-70-0
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      98-58-8
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      71-43-2
    • ~%
    • In-stock
      1-Bromo-4-(phenylsulfonyl)benzene|CS-W006340
      23038-36-0

    References

    • Recueil des Travaux Chimiques des Pays-Bas, , vol. 30, p. 139 Recueil des Travaux Chimiques des Pays-Bas, , vol. 33, p. 130,152 Chem. Zentralbl., , vol. 85, # I p. 2166
  • Route2
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      108-86-1
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      98-09-9
    • ~85%
    • In-stock
      1-Bromo-4-(phenylsulfonyl)benzene|CS-W006340
      23038-36-0

    References

    • Jin, Tongshou; Yang, Mina; Feng, Guoliang; Li, Tongshuang Journal of Chemical Research - Part S, 2003 , # 11 p. 721 - 723
  • Route3
    • null|null
      98-58-8
    • null|null
      71-43-2
    • ~%
    • In-stock
      1-Bromo-4-(phenylsulfonyl)benzene|CS-W006340
      23038-36-0

    References

    • Recueil des Travaux Chimiques des Pays-Bas, , vol. 30, p. 139 Recueil des Travaux Chimiques des Pays-Bas, , vol. 33, p. 130,152 Chem. Zentralbl., , vol. 85, # I p. 2166

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

Quality Control

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Computational Chemistry Data

  • TPSA   34.14
  • LogP   3.2819
  • H_Acceptors   2
  • H_Donors   0
  • Rotatable_Bonds   2

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