Benzyl (E)-prop-1-en-1-ylcarbamate

Name: Benzyl (E)-prop-1-en-1-ylcarbamate
Brand: ChemScene
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CAS No. 260967-14-4
Cat. No. CS-0108790
Purity≥98%
MDL No.MFCD30183516

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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Benzyl (E)-prop-1-en-1-ylcarbamate|CS-0108790

Structure of 260967-14-4

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Description

Benzyl (E)-prop-1-en-1-ylcarbamate features a stereodefined (E)-alkene moiety paired with a labile carbamate group, enabling selective deprotection under mild conditions. This bifunctional scaffold integrates seamlessly into synthetic sequences requiring orthogonal protection strategies. The benzyl ester component enhances solubility and facilitates purification.

Application

Benzyl (E)-prop-1-en-1-ylcarbamate serves as a stable, bench-friendly carbamate protecting group for amines, enabling selective deprotection under mild conditions. It functions effectively in multistep syntheses involving sensitive intermediates, with compatibility across diverse reaction types including hydrogenation and electrophilic functionalization. Its orthogonal stability to common protecting groups facilitates strategic synthesis planning in medicinal chemistry and API development.

General Information

CAS No. 260967-14-4
Cat. No. CS-0108790
Purity ≥98%
MDL No. MFCD30183516
Storage 4°C
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₁₁H₁₃NO₂
Molecular Weight 191.23
Synonym(s) (E)-benzyl prop-1-en-1-ylcarbamate
SMILES O=C(OCC1=CC=CC=C1)N/C=C/C

Computational Chemistry Data

TPSA 38.33
LogP 2.4464
H_Acceptors 2
H_Donors 1
Rotatable_Bonds 3

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Other Classifications

Building Blocks Functional Group Ester

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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Benzyl (E)-prop-1-en-1-ylcarbamate

CAS No. 260967-14-4

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