3-Amino-4-methylphenol

Name: 3-Amino-4-methylphenol
Brand: ChemScene
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CAS No. 2836-00-2
Cat. No. CS-W005693
Purity≥98%
MDL No.MFCD00075083

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

An item is classified as a dangerous good if our website displays Hazardous Material (HazMat) information for it.

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Structure of 2836-00-2

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Description

3-Amino-4-methylphenol features a strategically positioned amino group adjacent to a phenolic hydroxyl, enabling robust hydrogen bonding and enhanced solubility in polar solvents. This ortho-dipolar arrangement supports efficient coupling reactions and stabilizes intermediates under standard conditions. The methyl substituent introduces mild steric influence and electron-donating character, improving reactivity in electrophilic substitutions. Widely employed in pharmaceutical synthesis and dye chemistry, this compound delivers high functional group tolerance during multi-step transformations.

Application

3-Amino-4-methylphenol serves as a versatile building block in medicinal chemistry and agrochemical synthesis, enabling access to substituted phenolic scaffolds via standard coupling and functional group transformation protocols. Its ortho-difunctionalized structure—featuring an amino group adjacent to a hydroxyl—facilitates efficient heterocycle formation and provides excellent reactivity in electrophilic substitution and transition-metal-catalyzed cross-coupling reactions. The methyl group enhances metabolic stability and modulates electronic properties, while the compound exhibits good bench stability and ease of purification, making it well-suited for iterative synthetic workflows and scale-up applications.

General Information

CAS No. 2836-00-2
Cat. No. CS-W005693
Purity ≥98%
MDL No. MFCD00075083
Storage 4°C, protect from light
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₇H₉NO
Molecular Weight 123.15
Synonym(s) phenol, 3-amino-4-methyl-
SMILES OC1=CC=C(C)C(N)=C1

Computational Chemistry Data

TPSA 46.25
LogP 1.28282
H_Acceptors 2
H_Donors 2
Rotatable_Bonds 0

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Other Classifications

Building Blocks Functional Group Phenol

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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3-Amino-4-methylphenol

CAS No. 2836-00-2

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