5-Bromo-2-methylphenol

Name: 5-Bromo-2-methylphenol
Brand: ChemScene
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CAS No. 36138-76-8
Cat. No. CS-W008161
Purity≥97%
MDL No.MFCD08061906

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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Structure of 36138-76-8

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Description

5-Bromo-2-methylphenol features a bromine atom at the para position relative to a methyl-substituted phenolic hydroxyl group. This electron-deficient aromatic scaffold enables direct functionalization in cross-coupling reactions and serves as a key intermediate in pharmaceutical synthesis.

Application

5-Bromo-2-methylphenol serves as a versatile building block in synthetic organic chemistry, enabling efficient construction of substituted heterocycles and pharmaceutical intermediates. Its ortho-methyl and bromo substituents provide complementary reactivity for Suzuki-Miyaura coupling and electrophilic aromatic substitution, while the phenolic hydroxyl group offers direct functionalization potential. The compound exhibits good bench stability and facilitates straightforward purification, making it well-suited for iterative synthesis workflows in medicinal chemistry and process development.

General Information

CAS No. 36138-76-8
Cat. No. CS-W008161
Purity ≥97%
MDL No. MFCD08061906
Storage Store at room temperature
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₇H₇BrO
Molecular Weight 187.03
Synonym(s) Phenol,5-bromo-2-methyl-; 5-Bromo-2-methylphenol
SMILES BrC1=CC(=C(C=C1)C)O

Computational Chemistry Data

TPSA 20.23
LogP 2.46312
H_Acceptors 1
H_Donors 1
Rotatable_Bonds 0

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H315-H319-H335
Precautionary Statements : P261-P264-P271-P280-P302+P352

Quality Control

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Other Classifications

Building Blocks Functional Group Bromide

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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5-Bromo-2-methylphenol

CAS No. 36138-76-8

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