Lot numbers can be found on the outside label of a product:
(3-Bromoprop-1-yn-1-yl)trimethylsilane
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CAS No. 38002-45-8
- Cat. No. CS-W010730
- Purity≥95%
- MDL No.MFCD00134460
*For research and further manufacturing use only, not for direct human use.
Structure of 38002-45-8
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General Information
- CAS No. 38002-45-8
- Cat. No. CS-W010730
- Purity ≥95%
- MDL No. MFCD00134460
- Storage 4°C
- Shipping Room temperature in continental US; may vary elsewhere.
- Molecular Formula C₆H₁₁BrSi
- Molecular Weight 191.14
- Synonym(s) 3-Bromo-1-(trimethylsilyl)-1-propyne
- SMILES C[Si](C)(C#CCBr)C
Description
3-Bromo-1-(trimethylsilyl)-1-propyne is reported as a propargylating agent. Selective reaction of 3-bromo-1-(trimethylsilyl)-1-propyne with -keto ester using indium metal has been studied.3-Bromo-1-(trimethylsilyl)-1-propyne may be used in the preparation of tetrahydroisoquinoline-3-carboxylic acid derivatives. It may be used as reagent for the alkylation of dianion of -keto esters at -carbon. It may be employed in the preparation of terminal conjugated enynes and allenic alcohols.
Synthesis
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Route1
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36551-06-1 - ~83%
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In-stock
38002-45-8
References
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Schelper, Michael; De Meijere, Armin European Journal of Organic Chemistry, 2005 , # 3 p. 582 - 592
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Route2
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1066-54-2
- ~%
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In-stock
38002-45-8
References
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Wright, Justin M.; Jones, Graham B. Tetrahedron Letters, 1999 , vol. 40, # 43 p. 7605 - 7609
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Route3
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75-77-4
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In-stock
6089-04-9 - ~%
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In-stock
38002-45-8
References
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Josien, Hubert; David, Bom; Curran, Dennis P.; Zheng, Yu-Huang; Chou, Ting-Chao Bioorganic and Medicinal Chemistry Letters, 1997 , vol. 7, # 24 p. 3189 - 3194
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Safety Information
Download SDS|
GHS Pictogram :
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GHS No : GHS07
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Signal Word : Warning
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UN#: N/A
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Class : N/A
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Packing Group : N/A
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Hazard Statements : H302-H315-H319-H335
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Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501
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Quality Control
Computational Chemistry Data
- TPSA 0
- LogP 2.2621
- H_Acceptors 0
- H_Donors 0
- Rotatable_Bonds 0
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Key Words
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