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CS-W001157 4
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2-(Prop-2-yn-1-yloxy)tetrahydro-2H-pyran

  • CAS No. 6089-04-9

  • Cat. No. CS-0038687
  • Purity≥95%
  • MDL No.MFCD00006604

*For research and further manufacturing use only, not for direct human use.

2-(Prop-2-yn-1-yloxy)tetrahydro-2H-pyran|CS-0038687

Structure of 6089-04-9

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General Information

  • CAS No. 6089-04-9
  • Cat. No. CS-0038687
  • Purity ≥95%
  • MDL No. MFCD00006604
  • Storage 4°C, stored under nitrogen
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₈H₁₂O₂
  • Molecular Weight 140.18
  • Synonym(s) None
  • SMILES C#CCOC1OCCCC1

Description

The anion formed by metalation at the acetylenic carbon reacts with a variety of electrophiles.Tetrahydro-2-(2-propynyloxy)-2H-pyran was used in preparation of 1,3-dienyl acetal.

Synthesis

  • Route1
    • null|null
      110-87-2
    • null|null
      107-19-7
    • ~97%
    • In-stock
      2-(Prop-2-yn-1-yloxy)tetrahydro-2H-pyran|CS-0038687
      6089-04-9

    References

    • Williams, D. Bradley G.; Simelane, Sandile B.; Lawton, Michelle; Kinfe, Henok H. Tetrahedron, 2010 , vol. 66, # 25 p. 4573 - 4576
  • Route2
    • null|null
      110-87-2
    • null|null
      104-15-4
    • ~%
    • In-stock
      2-(Prop-2-yn-1-yloxy)tetrahydro-2H-pyran|CS-0038687
      6089-04-9

    References

    • US4254285 A1, ;
  • Route3
    • null|null
      64244-47-9
    • ~52%
    • In-stock
      2-(Prop-2-yn-1-yloxy)tetrahydro-2H-pyran|CS-0038687
      6089-04-9

    References

    • Caddick, Stephen; Murtagh, Lorraine; Weaving, Robert Tetrahedron Letters, 1999 , vol. 40, # 18 p. 3655 - 3656

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS02
Signal Word : Warning
UN#: 1993
Class : 3
Packing Group : Ⅲ
Hazard Statements : H226
Precautionary Statements : P210-P233-P240-P241-P242-P243-P280-P370+P378-P501

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Computational Chemistry Data

  • TPSA   18.46
  • LogP   1.1628
  • H_Acceptors   2
  • H_Donors   0
  • Rotatable_Bonds   2

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