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CS-W001157 4
Total: USD 88.00

m-Fluoronitrobenzene

  • CAS No. 402-67-5

  • Cat. No. CS-W018306
  • Purity≥97%
  • MDL No.MFCD00007196
  • HazMat Fee +

    HazMat Fee

    An item is classified as a dangerous good if our website displays Hazardous Material (HazMat) information for it. There is a HazMat shipping fee for each item that qualifies as a dangerous good, except in the following scenarios:

    The shipment is processed through FedEx Ground under the Limited Quantity option.

    Each bottle is packed as an Excepted Quantity, with a maximum of 1g for items in class 6.1 packing group I or II, and up to 25g for all other hazardous materials.

    If shipping is charged to your FedEx account, the HazMat fee will be billed directly by the courier. Otherwise, the fee will be included on your invoice. To help you avoid the HazMat fee, we can package a 5g order of a class 6.1 packing group I or II material as five separate 1g units, and a 100g order of any other dangerous good as four 25g units. This packaging adjustment will be made unless you instruct otherwise on your purchase order. Below, you will find the fee schedule from FedEx for handling hazardous materials.

    Type
    HazMat Fee
    Excepted Quantity $0.00
    FedEx Limited Quantities Ground $0.00
    Hazmat Ground shipping $50.00+
    Inaccessible (Haz class 6.1 or 9), Domestic $68.00+
    Accessible (Haz class 3, 4, 5 or 8), Domestic $158.00+
    Inaccessible (Haz class 6.1 or 9), International $108.00+
    Accessible (Haz class 3, 4, 5 or 8), International $238.00+

    An item is classified as a dangerous good if our website displays Hazardous Material (HazMat) information for it.

    There is a HazMat shipping fee for each item that qualifies as a dangerous good. Please contact our quotation team via email to confirm the details.

*For research and further manufacturing use only, not for direct human use.

m-Fluoronitrobenzene|CS-W018306

Structure of 402-67-5

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Description

1-Fluoro-3-nitrobenzene was used as an internal standard in the regiospecific silver-mediated fluorination of aryl silanes.

Application

1-Fluoro-3-nitrobenzene serves as a versatile bifunctional building block in synthetic organic chemistry, enabling directed ortho-metalation and transition-metal-catalyzed cross-coupling reactions. The fluorine and nitro groups exhibit complementary reactivity: the fluorine facilitates electrophilic substitution or nucleophilic aromatic substitution under mild conditions, while the nitro group acts as a strong electron-withdrawing director and can be readily reduced to an amine for further functionalization. Its bench stability and compatibility with standard purification methods make it a reliable intermediate in the synthesis of pharmaceuticals and agrochemicals.

General Information

  • CAS No. 402-67-5
  • Cat. No. CS-W018306
  • Purity ≥97%
  • MDL No. MFCD00007196
  • Storage Store at room temperature
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₆H₄FNO₂
  • Molecular Weight 141.10
  • Synonym(s) 1-Fluoro-3-nitrobenzene; 3-Fluoronitrobenzene; m-FNBZ
  • SMILES O=[N+](C1=CC(F)=CC=C1)[O-]

Computational Chemistry Data

  • TPSA   43.14
  • LogP   1.7339
  • H_Acceptors   2
  • H_Donors   0
  • Rotatable_Bonds   1

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS06,GHS08
Signal Word : Danger
UN#: 2810
Class : 6.1
Packing Group : Ⅱ
Hazard Statements : H412-H301+H311+H331-H315-H319-H335-H351-H373
Precautionary Statements : P260-P261-P264-P270-P271-P280-P302+P352-P304+P340-P330-P361-P363-P403+P233-P405-P501-P305+P351+P338-P332+P317-P337+P317-P362+P364-P273

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