4-Amino-N,N-dimethylbenzamide

Name: 4-Amino-N,N-dimethylbenzamide
Brand: ChemScene
Availability: InStock
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CAS No. 6331-71-1
Cat. No. CS-0071544
Purity≥98%
MDL No.None

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
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Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
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4-Amino-N,N-dimethylbenzamide|CS-0071544

Structure of 6331-71-1

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General Information

CAS No. 6331-71-1
Cat. No. CS-0071544
Purity ≥98%
MDL No. None
Storage 4°C, protect from light
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₉H₁₂N₂O
Molecular Weight 164.20
Synonym(s) N,N-DiMethyl 4-aMinobenzaMide
SMILES O=C(N(C)C)C1=CC=C(N)C=C1

Description

4-Amino-N,N-dimethylbenzamide features a para-amino group flanked by a sterically hindered dimethylamino substituent, enabling enhanced solubility and stability in polar solvents. This combination facilitates efficient coupling reactions in peptide synthesis and pharmaceutical intermediates.

Application

4-Amino-N,N-dimethylbenzamide serves as a versatile building block in medicinal chemistry, enabling the construction of diverse heterocyclic scaffolds and drug candidates. Its amine functionality facilitates facile derivatization via acylation, alkylation, or coupling reactions, while the dimethylamino group enhances solubility and modulates electronic properties. Bench-stable and readily purified by crystallization, it functions effectively in standard peptide coupling and transition-metal-catalyzed transformations.

Synthesis

Route1
- 7291-01-2
- ~10%
- In-stock
  
  6331-71-1
References
- Park, Sungho; Lee, In Su; Park, Jaiwook Organic and Biomolecular Chemistry, 2013 , vol. 11, # 3 p. 395 - 399
Route2
- 1016745-07-5
- ~56%
- In-stock
  
  6331-71-1
References
- AC Immune, S.A. Patent: US2011/280808 A1, 2011 ; Location in patent: Page/Page column 52 ;
Route3
- 122-04-3
- 124-40-3
- ~%
- In-stock
  
  6331-71-1
References
- US2010/15141 A1, ; Page/Page column 25-26 ; US 20100015141 A1

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

Quality Control

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Computational Chemistry Data

TPSA 46.33
LogP 0.9706
H_Acceptors 2
H_Donors 1
Rotatable_Bonds 1

Other Classifications

Building Blocks Functional Group Amide

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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4-Amino-N,N-dimethylbenzamide

CAS No. 6331-71-1

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