Lot numbers can be found on the outside label of a product:
Methyl 2-hydroxy-3-methoxybenzoate
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CAS No. 6342-70-7
- Cat. No. CS-W023091
- Purity≥96%
- MDL No.MFCD00239511
*For research and further manufacturing use only, not for direct human use.
Structure of 6342-70-7
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General Information
- CAS No. 6342-70-7
- Cat. No. CS-W023091
- Purity ≥96%
- MDL No. MFCD00239511
- Storage RT, stored under nitrogen
- Shipping Room temperature in continental US; may vary elsewhere.
- Molecular Formula C₉H₁₀O₄
- Molecular Weight None
- Synonym(s) Methyl 3-methoxysalicylate
- SMILES O=C(OC)C1=CC=CC(OC)=C1O
Description
Methyl 2-hydroxy-3-methoxybenzoate features a strategically positioned hydroxyl group and methoxy substituent on the aromatic ring, enabling selective derivatization in synthetic sequences. This ortho-hydroxy ester delivers enhanced solubility and stability under standard conditions, facilitating integration into complex molecular architectures.
Application
Methyl 2-hydroxy-3-methoxybenzoate serves as a versatile building block in synthetic organic chemistry, enabling efficient access to substituted phenolic scaffolds. Its ortho-hydroxyl and methoxy groups provide orthogonal reactivity for selective derivatization, while the methyl ester facilitates downstream transformations such as hydrolysis or cross-coupling. The compound exhibits good bench stability and is readily purified by standard chromatographic methods, making it well-suited for medicinal chemistry campaigns and process development workflows.
Synthesis
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Route1
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67-56-1 -
In-stock
877-22-5 - ~95%
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In-stock
6342-70-7
References
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Berryman; Edmunds; Bunker; Haleen; Bryant; Welch; Doherty Bioorganic and Medicinal Chemistry, 1998 , vol. 6, # 9 p. 1447 - 1456
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Route2
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In-stock
877-22-5
- ~93%
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In-stock
6342-70-7
References
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Assens, Jean-Louis; Bernhart, Claude; Cabanel-Haudricourt, Frederique; Gautier, Patrick; Nisato, Dino Patent: US2003/225100 A1, 2003 ; Location in patent: Page 23 ;
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Route3
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2150-42-7 - ~90%
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In-stock
6342-70-7
References
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Sudo, Yukinori; Arai, Shigeru; Nishida, Atsushi European Journal of Organic Chemistry, 2006 , # 3 p. 752 - 758
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Safety Information
Download SDS|
GHS Pictogram :
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GHS No : GHS07
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Signal Word : Warning
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UN#: N/A
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Class : N/A
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Packing Group : N/A
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Hazard Statements : H315-H319-H335
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Precautionary Statements : P260-P264-P271-P280-P302+P352-P304+P340-P305+P351+P338-P332+P313-P337+P313-P362+P364-P403+P233-P405-P501
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Quality Control
Computational Chemistry Data
- TPSA 55.76
- LogP 1.1874
- H_Acceptors 4
- H_Donors 1
- Rotatable_Bonds 2
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Key Words
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