2-Bromo-4-fluoronitrobenzene

Name: 2-Bromo-4-fluoronitrobenzene
Brand: ChemScene
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CAS No. 700-36-7
Cat. No. CS-D1760
Purity≥97%
MDL No.MFCD00792441

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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Description

2-Bromo-4-fluoronitrobenzene is a highly reactive aryl halide featuring complementary electrophilic sites for cross-coupling and nucleophilic substitution. The para-fluoro group enables selective displacement under mild conditions, while the ortho-bromo moiety facilitates palladium-catalyzed coupling reactions. This bifunctional architecture supports efficient access to complex aromatic scaffolds in pharmaceutical and agrochemical synthesis.

Application

2-Bromo-4-fluoronitrobenzene serves as a versatile building block in cross-coupling chemistry and heterocycle synthesis, enabling efficient construction of biaryl and functionalized aromatic scaffolds. Its complementary halogenation pattern—bromine at C2 and fluorine at C4—facilitates selective metalation and transition-metal-catalyzed transformations. The molecule exhibits excellent bench stability and compatibility with palladium-catalyzed coupling protocols, offering predictable reactivity and straightforward purification.

General Information

CAS No. 700-36-7
Cat. No. CS-D1760
Purity ≥97%
MDL No. MFCD00792441
Storage Store at room temperature
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₆H₃BrFNO₂
Molecular Weight 220.00
Synonym(s) 2-Bromo-4-fluoro-1-nitrobenzene
SMILES O=[N+](C1=CC=C(F)C=C1Br)[O-]

Computational Chemistry Data

TPSA 43.14
LogP 2.4964
H_Acceptors 2
H_Donors 0
Rotatable_Bonds 1

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Other Classifications

Building Blocks Functional Group Nitro compounds

Building Blocks Functional Group Bromide

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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2-Bromo-4-fluoronitrobenzene

CAS No. 700-36-7

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