4-Bromo-2-methoxyphenol

Name: 4-Bromo-2-methoxyphenol
Brand: ChemScene
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CAS No. 7368-78-7
Cat. No. CS-W007865
Purity≥96%
MDL No.MFCD00051937

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
Accessible (Haz class 3, 4, 5 or 8), International	$238.00+

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Structure of 7368-78-7

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Description

4-Bromo-2-methoxyphenol offers a strategically positioned bromine atom and methoxy group on the phenolic scaffold, enabling selective functionalization in cross-coupling reactions. This electron-rich aryl halide integrates readily into complex molecular architectures under standard conditions.

Application

4-Bromo-2-methoxyphenol serves as a versatile building block in medicinal chemistry, enabling direct functionalization at the phenolic hydroxyl and ortho-position via palladium-catalyzed cross-coupling. Its bromine atom facilitates Suzuki, Stille, and Negishi reactions, while the methoxy group provides moderate electron donation and orthogonal protection potential. The compound exhibits good bench stability and is readily purified by column chromatography, making it well-suited for iterative synthesis of bioactive heterocycles and pharmaceutical intermediates.

General Information

CAS No. 7368-78-7
Cat. No. CS-W007865
Purity ≥96%
MDL No. MFCD00051937
Storage 4°C
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₇H₇BrO₂
Molecular Weight 203.03
Synonym(s) 4-Bromoguaiacol
SMILES OC1=CC=C(Br)C=C1OC

Computational Chemistry Data

TPSA 29.46
LogP 2.1633
H_Acceptors 2
H_Donors 1
Rotatable_Bonds 1

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

Quality Control

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Other Classifications

Bioactive Molecules Dye and Bio-assay Reagents

Building Blocks Functional Group Phenol

Building Blocks Functional Group Bromide

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Key Words

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4-Bromo-2-methoxyphenol

CAS No. 7368-78-7

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