6-Bromo-7-methylimidazo[1,2-a]pyridine

CAS No. 116355-18-1
Cat. No. CS-0085039
Molecule weight211.06
Purity≥97%
MDL No.MFCD09258769

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Type	HazMat Fee
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6-Bromo-7-methylimidazo[1,2-a]pyridine|CS-0085039

Structure of 116355-18-1

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General Information

CAS No. 116355-18-1
Cat. No. CS-0085039
Purity ≥97%
MDL No. MFCD09258769
Storage 4°C
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₈H₇BrN₂
Molecular Weight 211.06
Synonym(s) None
SMILES BrC(C(C)=C1)=CN2C1=NC=C2

Description

6-Bromo-7-methylimidazo[1,2-a]pyridine is a heterocyclic building block featuring a brominated imidazopyridine core with a methyl substituent at the 7-position. This scaffold delivers enhanced electronic modulation and steric profile, enabling efficient coupling in transition metal-catalyzed reactions. The compound exhibits bench-stable handling characteristics and serves as a key intermediate in medicinal chemistry and materials science applications.

Application

6-Bromo-7-methylimidazo[1,2-a]pyridine serves as a versatile heterocyclic building block for medicinal chemistry and catalytic coupling reactions. The bromine at the 6-position enables palladium-catalyzed cross-coupling, while the methyl group at the 7-position enhances solubility and modulates electronic properties. This compound exhibits good bench stability and facilitates efficient functionalization in standard synthetic workflows, making it well-suited for constructing complex imidazopyridine-based scaffolds.

Synthesis

Route1
- 107-20-0
- In-stock
  
  98198-48-2
- ~96%
- In-stock
  
  116355-18-1
References
- AGENCY FOR SCIENCE, TECHNOLOGY AND RESEARCH; NACRO, Kassoum; DURAISWAMY, Athisayamani, Jeyaraj; CHENNAMANENI, Lohitha, Rao Patent: WO2013/147711 A1, 2013 ; Location in patent: Page/Page column 207 ;

Safety Information

Download SDS

GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H302-H315-H319-H335
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501

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Computational Chemistry Data

TPSA 17.3
LogP 2.40522
H_Acceptors 2
H_Donors 0
Rotatable_Bonds 0

Other Classifications

Building Blocks Skeleton Aromatic heterocycle compounds Imidazole compounds

Building Blocks Skeleton Aromatic heterocycle compounds Pyridine compounds

Key Words

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6-Bromo-7-methylimidazo[1,2-a]pyridine

CAS No. 116355-18-1

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