Fmoc-PNA-A(Bhoc)-OH

Name: Fmoc-PNA-A(Bhoc)-OH
Brand: ChemScene
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CAS No. 186046-82-2
Cat. No. CS-0621854
Purity≥95%
MDL No.MFCD01940757

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Type	HazMat Fee
Excepted Quantity	$0.00
FedEx Limited Quantities Ground	$0.00
Hazmat Ground shipping	$50.00+
Inaccessible (Haz class 6.1 or 9), Domestic	$68.00+
Accessible (Haz class 3, 4, 5 or 8), Domestic	$158.00+
Inaccessible (Haz class 6.1 or 9), International	$108.00+
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Structure of 186046-82-2

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General Information

CAS No. 186046-82-2
Cat. No. CS-0621854
Purity ≥95%
MDL No. MFCD01940757
Storage 4°C
Shipping Room temperature in continental US; may vary elsewhere.
Molecular Formula C₄₀H₃₅N₇O₇
Molecular Weight 725.75
Synonym(s) None
SMILES O=C(CN(CCNC(OCC1C2=C(C3=C1C=CC=C3)C=CC=C2)=O)C(CN4C=NC5=C4N=CN=C5NC(OC(C6=CC=CC=C6)C7=CC=CC=C7)=O)=O)O

Description

Fmoc-PNA-A(Bhoc)-OH is a protected monomer designed for solid-phase peptide nucleic acid synthesis. The Fmoc group enables orthogonal deprotection, while the Bhoc-protected amine ensures selective coupling. This derivative integrates seamlessly into PNA backbones, offering enhanced solubility and stability during sequence assembly.

Application

Fmoc-PNA-A(Bhoc)-OH serves as a key building block in the synthesis of peptide nucleic acid (PNA) oligomers, enabling site-specific incorporation of A (adenine) analogs with orthogonal protection. The Fmoc group ensures efficient stepwise solid-phase synthesis, while the Bhoc (benzyloxycarbonyl) moiety provides stable protection for the amine, allowing selective deprotection under mild conditions. This derivative exhibits excellent bench stability, compatibility with standard coupling reagents, and facilitates high-yielding conjugations in PNA backbone assembly.

Safety Information

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GHS Pictogram :	GHS No : GHS07
Signal Word : Warning	UN#: N/A
Class : N/A	Packing Group : N/A
Hazard Statements : H315-H319
Precautionary Statements : P264-P280-P302+P352-P305+P351+P338-P362+P364

Quality Control

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Computational Chemistry Data

TPSA 177.87
LogP 5.6163
H_Acceptors 10
H_Donors 3
Rotatable_Bonds 13

Other Classifications

Building Blocks Functional Group Fmoc

Building Blocks Functional Group Ester

Building Blocks Skeleton Aromatic heterocycle compounds Purine compounds

Building Blocks Skeleton Aromatic ring compounds Benzene compounds

Chemical Biology Pharmaceutical Development and Drug Discovery Research Nucleic Acid Chemistry Peptide Nucleic Acid (PNA) Monomers

Chemical Biology Pharmaceutical Development and Drug Discovery Research Peptide Chemistry Amino Acid Derivatives

Chemical Biology Pharmaceutical Development and Drug Discovery Research Peptide Chemistry Unnatural Amino Acid Derivatives

Chemical Biology Pharmaceutical Development and Drug Discovery Research Reagents Nucleic Acid Chemistry Peptide Nucleic Acid (PNA) Monomers

Chemical Biology Pharmaceutical Development and Drug Discovery Research Reagents Peptide Chemistry Amino Acid Derivatives

Chemical Biology Pharmaceutical Development and Drug Discovery Research Reagents Peptide Chemistry Unnatural Amino Acid Derivatives

Chemical Biology Peptide Chemistry Amine Protection

Chemical Biology Peptide Chemistry Amino Acid Derivatives

Biochemistry Biochemicals and Reagents Amino Acids N-Protected Amino Acids

Key Words

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Fmoc-PNA-A(Bhoc)-OH

CAS No. 186046-82-2

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