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CS-W001157 4
Total: USD 88.00

Carbonyldihydridotris(triphenylphosphine)ruthenium(II)

  • CAS No. 25360-32-1

  • Cat. No. CS-0081066
  • Purity≥98%
  • MDL No.MFCD00015870

*For research and further manufacturing use only, not for direct human use.

Carbonyldihydridotris(triphenylphosphine)ruthenium(II)|CS-0081066

Structure of 25360-32-1

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General Information

  • CAS No. 25360-32-1
  • Cat. No. CS-0081066
  • Purity ≥98%
  • MDL No. MFCD00015870
  • Storage 4°C, protect from light, stored under nitrogen
  • Shipping Room temperature in continental US; may vary elsewhere.
  • Molecular Formula C₅₅H₄₇OP₃Ru
  • Molecular Weight 917.97
  • Synonym(s) Carbonyl(dihydrido)tris(triphenylphospineruthenium (II)
  • SMILES [RuH2][P](C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3.[C-]#[O+]

Description

Catalyst for conversion of 1,4-alkynediols into pyrroles Catalyst for oxidation of primary alcohols to methyl esters Catalyst for rearrangement of oximes to amides Catalyst for C-C coupling via directed C-H activation Catalyst for enyne cyclization

Synthesis

  • Route1
    • null|null
      157072-60-1
    • ~93%
    • In-stock
      Carbonyldihydridotris(triphenylphosphine)ruthenium(II)|CS-0081066
      25360-32-1

    References

    • Boniface, Suzanne M.; Clark, George R.; Collins, Terrence J.; Roper, Warren R. Journal of Organometallic Chemistry, 1981 , vol. 206, # 1 p. 109 - 117
  • Route2
    • Dihydrido(dihydrogen)tris(triphenylphosphine)ruthenium|CS-0782464
      114595-94-7
    • ~%
    • In-stock
      Carbonyldihydridotris(triphenylphosphine)ruthenium(II)|CS-0081066
      25360-32-1

    References

    • Sluys, Lori Stepan Van Der; Kubas, Gregory J.; Caulton, Kenneth G. Organometallics, 1991 , vol. 10, p. 1033 - 1038
  • Route3
    • trans-Dihydrotetrakis(triphenylphosphine)ruthenium|CS-0782473
      27599-25-3
    • null|null
      14353-75-4
    • ~49%
    • In-stock
      Carbonyldihydridotris(triphenylphosphine)ruthenium(II)|CS-0081066
      25360-32-1
    • Ruthenium, hydro[(1,2,3,4,5-η)-6-oxo-2,4-cyclohexadien-1-yl]bis(triphenylphosphine)-|CS-0782477
      61817-37-6

    References

    • Yamamoto, Takakazu; Miyashita, Satoshi; Naito, Yoshiyuki; Komiya, Sanshiro; Ito, Takashi; Yamamoto, Akio Organometallics, 1982 , vol. 1, p. 808 - 812

Safety Information

Download SDS
GHS Pictogram :
GHS No : GHS07
Signal Word : Warning
UN#: N/A
Class : N/A
Packing Group : N/A
Hazard Statements : H302+H312+H332
Precautionary Statements : P261-P264-P270-P271-P280-P302+P352-P304+P340-P330-P362+P364-P501

Quality Control

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Computational Chemistry Data

  • TPSA   19.9
  • LogP   3.13709
  • H_Acceptors   0
  • H_Donors   0
  • Rotatable_Bonds   3

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